Compliant morphing structures from twisted bulk metallic glass ribbons

In this work, we investigate the use of pre-twisted metallic ribbons as building blocks for shape-changing structures. We manufacture these elements by twisting initially flat ribbons about their (lengthwise) centroidal axis into a helicoidal geometry, then thermoforming them to make this configuration a stress-free reference state. The helicoidal shape allows the ribbons to have preferred bending directions that vary throughout their length. These bending directions serve as compliant joints and enable several deployed and stowed configurations that are unachievable without pre-twist, provided that compaction does not induce material failure. We fabricate these ribbons using a bulk metallic glass (BMG), for its exceptional elasticity and thermoforming attributes. Combining numerical simulations, an analytical model based on a geometrically nonlinear plate theory and torsional experiments, we analyze the finite-twisting mechanics of various ribbon geometries. We find that, in ribbons with undulated edges, the twisting deformations can be better localized onto desired regions prior to thermoforming. Finally, we join multiple ribbons to create deployable systems with complex morphing attributes enabled by the intrinsic chirality of our twisted structural elements. Our work proposes a framework for creating fully metallic, yet compliant structures that may find application as elements for space structures and compliant robots

Determination of critical cooling rates in metallic glass forming alloy libraries through laser spike annealing

The glass forming ability (GFA) of metallic glasses (MGs) is quantified by the critical cooling rate (R C). Despite its key role in MG research, experimental challenges have limited measured R C to a minute fraction of known glass formers. We present a combinatorial approach to directly measure R C for large compositional ranges. This is realized through the use of compositionally-graded alloy libraries, which were photo-thermally heated by scanning laser spike annealing of an absorbing layer, then melted and cooled at various rates. Coupled with X-ray diffraction mapping, GFA is determined from direct R C measurements. We exemplify this technique for the Au-Cu-Si system, where we identify Au56Cu27Si17 as the alloy with the highest GFA. In general, this method enables measurements of R C over large compositional areas, which is powerful for materials discovery and, when correlating with chemistry and other properties, for a deeper understanding of MG formation